New technologies for predicting corrosion and modelling

Full-field measuring techniques of wind blade working conditions

INEGI is developing a non-destructive testing system (NDT) which is intended as a first version of the final blade testing system to be developed in the coming months. The main results achieved include the definition and execution of NDT laboratory setups using DIC and IR solutions, the selection of the necessary equipment, as well as the development and successful use of the proposed trigger solutions.

Concerning the digital image correlation analyzes, two first approaches have already been carried out, namely the establishment of a system for evaluating displacements using static cameras with static blades, and them using static cameras with a rotating blade. For the defect detention system using thermography, several approaches were evaluated, and the most successful was found to be the use of an algorithm that does image comparison between thermographic images, one with a defect-free blade, used as a reference and one as the test subject.

DIC laboratorial setup and IR testing setup for testing wind blades working conditions
Figure 1. DIC laboratorial setup (left),  IR testing setup (right)

INEGI will continue with the presented plan and carry on with the remaining activities, especially with regard to the development using the structure from motion approach to carry out DIC analyzes with floating cameras, as well as with the establishment of the limits and strengths of the different thermographic approaches.

 

Implementation and assessment of FBGs/DFOs technologies

INEGI found that the materialization of several SHM laboratorial setups using both FBG and DFO technologies was successful, and validated the assumptions and decisions that were made, thus being ready to be implemented in the real-life scenario SHM.

Likewise, CETMA has shown the feasibility of FO distributed sensors to be applied as monitoring system in reinforced concrete structures. In particular, the developed SMART rebars (i.e., rebars with embedded FO sensors) show the following essentials points:

      • An SHM system based on SMART rebars with distributed FO sensors can provide thousands of sensing points that permits mapping of strain distributions the reinforcement of the structure.

      • The FO sensors provide the same results of traditional strain sensors in terms of reliability, with many advantages among which multiparameter measurements with the same sensor, no need of recalibration, easier wiring, high resistance in hard environment.

      • The developed embedding near surface technique of the FO sensors in the rebars is easy to realize and reliable; validation results on tensile strength test showed good behaviour.

      • The developed decoupling system permits to create segments of FO sensors not subjected to mechanical stresses.

      • The lab-trials related to the embedding process of SMART rebars demonstrated that the developed technique for the protection of the sensor in the inlet/outlet points of the FO cables both from the rebar and the concrete works properly; a 100% rate survival was achieved for all the typologies of concretes.

      • The lab trials related to mechanical tests on concrete elements with SMART rebars inside demonstrated the capability of the developed SHM system to properly detect different typologies of mechanical stresses (i.e., flexural, compression).

The activities developed will be used and furtherly implemented for SHM system for blade monitoring and concrete structures monitoring.

 

Modelling of GBS structure and influence of tested materials

INEGI finds as main results the definition of the design of the GBS and the study of the environmental conditions of the test site, as well as the numerical study of the structural forces on the GBS coming from the sea states and the transport and handling processes.

They also identified as the main next step to carry the planning and definition of the open sea test to be executed within the context of this project. Additionally, INEGI will continue to perform FEM simulation to study the structural integrity of the structure.

 

Development and validation of FEA model of composite structure for blades

The results from the MAREWIND Excel tool for the calculation of the transverse elastic and shear modulus show a better agreement with the available data using the Halpin-Tsai equations instead of the constant stress model. The MAREWIND tool has been validated for both the micro-mechanical and macro-mechanical part. Concerning the micro mechanical validation, good agreement with the reference results has been obtained. The Halpin-Tsai results are in excellent agreement with a negligible deviation.

The stress and strain calculated show excellent agreement with the reference results. Failure Analysis was performed with a unidirectional load in order to validate Tsai-Hill Failure Theory of Excel Tool and also in this case, the obtained results show an excellent agreement with the reference ones.

Likewise, the FE model tool has been validated for both the micro-mechanical and macro-mechanical part. For the macro-mechanical model, the deviations are smaller than 1% and therefore the experimental results of the literature and the numerical ones are in excellent agreement. Thus, both the micro- and macro-mechanical FE models can be considered validated.

The objective will be to use the high-resolution FE model of composite and tool to compare their results against the experimental data that will be made available by partners performing tests on the materials selected for the next phases of the project. The obtained results will be the basis for conducting the activities foreseen referred to the simulation of the blade prototype (or part of it) predict the fatigue life of the wind turbines.

A fouling-preventing coating for different materials of offshore submerged structures has been developed and characterised at laboratory scale. In the first steps, two different base coatings were developed: low curing temperature and higher curing temperature.

The complete system, in both cases, implied a two-layer treatment, with a second thin layer focused in reducing the contact of the biological matter to the surface of the different materials. In the last months, based on a room temperature curing strategy, TECNAN and Lurederra developed a one layer system with oleo and hydrophobic final properties as the two other systems. All of these base matrixes and the one-layer system matrix, have similar colour, density, viscosity and stability overtime.

In addition, samples of materials with different chemical nature were selected in order to apply and validate the coating formulations. In particular, these materials are metal, painted metal and various polymers.

 

Applications of the antifouling coatings

The application selected was the spray gun because of its versatility for the target substrates. TECNAN has been working in the adjustment of the parameters such as the atomisation pressure, liquid flow and the fan width among others.

In the particular case of the hydrophobic properties, considering that the contact angle 90º is a good result reference, the values obtained of the different substrates tested in all the treatments developed, are quite inspiring.

Hydrophobic properties on stainless steel and painted metal
Figure 1. Hydrophobic properties on stainless steel (Matrix C) and painted metal (Matrix A + top coat)

In the case of the repellence of oil, very good results have been obtained too, not only in metal but also in polymeric substrates which have low reactivity and some initial repellence that imply a bigger challenge to generate a suitable and functional coating layer on it.

Cross-cut test on EDF coupons, oleophobic effect in polyamide and POM and roughness measurement on polyethylene
Figure 2. Cross-cut test on EDF coupons, oleophobic effect in polyamide and POM and roughness measurement on polyethylene

As a consequence, we could highlight the good results with the latest developed formulation based on one layer and low curing temperature, in relation with the adherence and compatibility with the substrates and the final repellence properties. The future work on the technologies validation and manufacturing, will be following this formulation strategy.

 

Tests in real environments

Enerocean in close cooperation with Lurederra and Tecnan, also defined and prepared the samples for the regulations ASTM D3623 and ASTM D5479, with the selected formulation ©. The materials selected for these tests were Nylon as the polymeric substrate and stainless steel as the metallic substrate. Enerocean was in charge of getting the samples and Lurederra of coating them with the protocols from Tecnan.

EDF polymeric coupons coated and the two substrates (metal and polymer) sent to Enerocean once coated
Figure 3. EDF polymeric coupons coated and the two substrates (metal and polymer) sent to Enerocean once coated
 

Evaluation of the coatings

EDF has carried out studies on the evaluation of the coatings. Currently, antifouling coatings are subjected to a series of conditions in order to be suitable for real applications and also, the performance must be determined by three properties:

  • Ability to limit biofouling
  • Low fouling adhesion and resistance of the coating to mechanical
  • Chemical damages

Products belonging to the range of Chugoku Marine Paints have been selected in order to carry out comparative testing with the new solutions in development. These products consist of two different layers: ECOMAX Bi (base coat) and BIOCLEAN ECO (top coat), and it is based on non-biocidal technology. Lurederra and Tecnan have applied it and tested it on some substrates showing that the final thickness of the mentioned commercial product layers is quite significant meaning that the weight of the structures can increase in a considerable way, its appearance can change and the application can be extremely difficult.

Polycarbonate piece coated with commercial product and the hydrophobic properties
Figure 4. Polycarbonate piece coated with commercial product and the hydrophobic properties

Based on the commercially available systems, the selection of the wind turbine blade coating for trials was undertaken. In order to achieve the desired repellence (superhydrophobicity) and erosion resistance, TWI has incorporated functional additives into the selected coating matrix. All selected additives were based on materials which have previously been demonstrated to be platforms for superhydrophobic surfaces.

These additives are inorganic metal oxides that are capable of surface functionalisation to enable their native hydrophilic surfaces to be transformed into exhibiting hydrophobic behaviour. The key additives explored are:

  • Stöber derived TWI silica

  • Metal oxides (TECNAN’s silica manufactured using pyrogenic methods and commercially available pyrogenic silica Aerosil 200)

TECNAN's SiO2 functionalized with HMDZ (left) and f-HMDZ (right) deposited onto glass slides
Figure 1. TECNAN’s SiO2 functionalized with HMDZ (left) and f-HMDZ (right) deposited onto glass slides.

 

Comparison of contact angle between silica powder without (left) and with (right) HDMZ treated silica product added
Figure 2. The particle functional performance change associated with surface functionalization. Trimethylsilylation is capable of changing pyrogenic silica behaviour from hydrophilic to superhydrophobic.

The mentioned functionalized silicas were incorporated into PU model matrix system in a various combinations and various loading levels. TWI have undertaken wettability, abrasion, adhesion and chemical resistance tests, whereas EIRE took care of rain erosion examination. INL have been given coated samples to perform long-term weatherability study.

All developed coatings improved the repellent characteristics of commercial model matrix system. Satisfactory results were also obtained from adhesion, abrasion and chemical durability tests. Nevertheless, the erosion resistance of those coatings was still not reaching target values and therefore, second generation coatings were developed.

 

Next steps

Further minor coating modifications will be done – addition of second functionalization might be necessary in order to bind silica particles with model matrix system via covalent bonding and thus, to increase the resistance towards rain erosion. The result from the rain erosion study suggested that developed coatings were too hard and this is not beneficial in terms of providing the resistance towards flowing water. Therefore, silica microparticles won’t be functionalized at all, to prevent and increased hardness caused from bonding together or to the matrix.

 

During the first 18 months of the project, the MAREWIND Consortium has been working on the development of an anticorrosion coating for key metallic elements. The coating consists of three layers with different chemical compositions and, therefore, different corrosion protections. Moreover, the multilayer system has been developed layer by layer:

  • Layer 1 has a metallic composition providing the substrate with a good cathodic protection. Considering the low curing temperature and stability overtime, two main matrix formulations were investigated, as well as various metallic components and loads.

  • Layer 2 incorporates a self-healing system based on core-shell micro/nanofibers. Nanofibers were produced and optimized regarding viscosity of each material and prepared by electrospinning technique. Then, they were completely characterised in terms of textural, morphological and chemical properties, revealing an increase in corrosion protection close to 40 times.

  • Layer 3 was designed as an Organic Inorganic Hybrid (OIH) sol-gel matrix with reinforcements of fibres and ceramic nanoparticles. The formulation has been adapted and optimised to provide the coating with additional properties such as increased mechanical strength and hydrophobicity to protect even more the target metallic offshore structures.

Multilayer system with different chemical composition and corrosion protections
Figure 1. Multilayer system with different chemical composition and corrosion protections

Different systems were proposed regarding matrices and curing procedures at low, medium and high temperature. Also, an exhaustive work regarding coating application methods as well as the characterisation of coated samples has been performed. With these results, finally the system of anticorrosion coating has been achieved in low temperature strategy.

Coating application systems

Two strategies were designed for this purpose:

  • Application via spray gun:

    A suitable procedure depends on the adjustment of the spray gun parameters to obtain uniform and smooth coatings. TECNAN was able to generate a reference protocol for each layer defining main parameters involved in the application process such as atomization pulverization, flow rate.

  • Application via dip coating:

    Dip coating is more appropriate for applying the coatings on a large number of small metallic elements. A small-scale device has been designed for a preliminary adjustment of the coating application.

 

The results show that spraying is the main alternative, since it provides a good surface finish, being applicable for different morphologies and sizes, while immersion is more focused on small elements with very complex geometries. Also a successful application of whole protections systems has been carried out, revealing good interactions between layers.

Characterisation of the coatings

This step was performed in Lurederra’s laboratory and saline mist chamber, INL facilities and TSF specific assessment. In this context, it took place the characterisation of the treated samples in terms of performances for each corrosion protection system, regarding adherence, corrosion resistance, hardness, among others. Complementary information has been generated related to microstructure, textures, defects and surface details.

The investigations showed promising results regarding corrosion protection, reaching to more than 4.200 hour of protection in saline mist chamber and successfully comply with corrosion aging test including exposure to salt spray in combination with UV, water condensation and freezing conditions according to ISO 12944-9.

Real samples inside the saline chamber showing no corrosion, and UV resistance tests carried out on flat samples for aging validation
Figure 2. Real samples inside the saline chamber showing no corrosion, and UV resistance tests carried out on flat samples for aging validation

MAREWIND TOWARDS A MORE ECONOMIC AND SUSTAINABLE OFFSHORE WIND SECTOR

MAREWIND project will develop durable materials and recyclable solutions for the offshore wind industry, while extending the service life of the wind facilities and creating new job opportunities.

Nowadays, the wind turbine blade leading-edge erosion affects the annual energy production by 4-20 %. That equates to a loss between €152-760 million a year across the overall European offshore wind sector. Moreover, the maintenance of the materials is very expensive and accounts for around 25% of the offshore wind farms’ cost. In addition to that, at the end of the wind turbines’ service life, the generated waste in need of recycling can increase up to 800,000 tones per year in Europe by 2050.

MAREWIND solutions will pave the way for the next generation offshore wind generators and facilities that aim to solve the technological, economical, business, and societal challenges we are now facing. In addition, it will strengthen the leading role of Europe in the global offshore wind market with current 22,072 MW of installed cumulative capacity, followed by Asian and North America markets.

Meet the consortium

Progress achieved after 18th months

It has been a busy and productive first phase of the project MAREWIND project. Since its launch in December 2020, the MAREWIND team has been working hard on progressing to achieve the ambitious goals of the project. The project addresses the main aspects related to materials durability and maintenance in offshore structures which have the potential to reduce imply failure, misfunctioning, loss of efficiency in energy generation and which have a major repercussion on O&M and CAPEX. MAREWIND aims to develop durable materials and recyclable solutions for the offshore wind industry, while extending the service life of the wind facilities. In addition, the project outcomes will also contribute to meeting the EU climate targets and create new job opportunities within the wind industry.  

MAREWIND project has achieved its second milestone!

Second milestone of the project has been successfully achieved! During the first year and a half, most of the technical work done by the partners has focused on the fabrication and testing elements individually. Specific formulations have been selected after testing and checking accelerated essays which comply with technical requirements. A great progress has been done thanks to the close collaboration between the partners of MAREWIND consortium. We are looking forward to sharing the outcomes we will achieve in the upcoming years!

Next steps

The consortium is preparing its third newsletter, so stay tuned for more details about the progress achieved so far. You can subscribe for the latest MAREWIND news and events, here.

MAREWIND is developing innovative structural health monitoring (SHM) systems for blades and foundation structures of offshore wind farms.

Full-field measuring techniques of wind blade working conditions: hardware, measurements and algorithms

In Task 3.1, INEGI is developing a non-destructive testing system which will be a mock-up of the final blade SHM system to be implemented in the following work packages. This system will consist of the use of a drone-supported configuration to perform digital image correlation (DIC) and thermographic analyses to monitor the appearance of surface and subsurface defects on wind turbine blades. At this stage, INEGI has already worked on the preliminary studies to define and design the laboratory testing setups to be carried out and on the selection of all the necessary equipment (Figure 1). Subsequently, INEGI also started to work on the synchronized trigger and control solution related to the DIC analyses.

Finally, with regard to image acquisition and processing tasks, INEGI has already performed some test setups for DIC and infrared (IR) analysis. For the future, INEGI will focus on the implementation of all proposed configurations for the validation of the proposed technology and will also work on the development of the data analysis software necessary for the implementation of the real-case scenario.

Figure1: DIC testing setup.
 

Implementation and assessment of FBGs/DFOs technologies for composite

Likewise, in Task 3.2, INEGI is responsible for the development and implementation of embedded fibre optical (FO) sensors for representative laboratory composite components. As of this date, INEGI has already worked on defining the location of the sensors for all the variables to be assessed, defining the equipment used for each parameter evaluated and started its procurement process.

In addition to this, INEGI has already run three test setups with representative parts instrumented with both conventional strain gauges and Fibre Bragg grating (FBG) sensors (2), which allowed to validate the proposed sensor placement, access the sensor bonding process and start developing the data acquisition and processing software. For the future, INEGI plans to complete the execution of all the proposed configurations and to work on the development of the data acquisition and processing software.

Figure 2: Testing setup with wind turbine blade representative part and FBG sensors.

In the same Task 3.2, CETMA is responsible for the development and implementation of the innovative SHM system, based on FO, that will be used for monitoring the foundation structures of offshore wind farms. Prototypes of the foundation structures to be built with the new mixtures were defined, based on a new design, in collaboration with the other partners involved; the SHM monitoring system was defined in terms of number and positions of points to be monitored, frequency of acquisition, parameters to be monitored and costs of equipment and sensors. All these parameters brought to the definition of SHM system based on distributed FO sensors to be apply on composite rebars in the concrete structures. In the next months, CETMA will carry out lab trials on the SHM system to demonstrate the suitability of the designed solution to the application.

Water simulations around gravity-based structures

In Task 3.3, INEGI will develop models to recreate the operational conditions of a Ground Based Structure (GBS). These models will consider three scenarios: transport to the installation site, installation and operation. With the information provided by these models and using machine learning algorithms it will be possible to obtain information about the GBS in real environment aiming the decision of the need of maintenance.

At this stage, the Computational Fluid Dynamics (CFD) numerical simulations that model the water flow around the GBS are running, with some results already obtained. This data follows to Fluid-Structure Interaction (FSI) models to quantify the efforts on the GBS (Figure 3). The machine learning models were already developed and are ready to be trained with the data produced by CFD and FSI models.

Figure 3: Simulations of GBS transport and installation.

Structural analyses on composite blades

In the period M4-M12, RINA has continued the development of a mathematical model of the composite blade materials by developing the high-resolution finite element model for composite blades (Figure 4). In addition, RINA has developed a MS Excel tool able to perform a preliminary micro- and macro-mechanical analysis on flat composite structures made of unidirectional fabrics. Both the tool and finite element model have been preliminarily validated with a reference composite structure (experimental data available and provided by the partner EIRE Composites).

 
Figure 4: Geometry (left) and mesh (right) of the Representative Volume Element (RVE) selected for the finite element model.

The next steps will consist in performing a more accurate calibration and validation of the high-resolution finite element model of composite and tool, also testing the in-use materials selected for the development of the prototype. The results will be the basis for conducting the activities referred to the simulation of the blade prototype (or part of it) to predict the fatigue life of the wind turbines.

Modelling of corrosion in atmosphere-exposed metallic structures

From month 6 to month 12, IDENER continued the formulation of a corrosion mathematical model that considers the protection of the metallic surface with an anticorrosion coating layer. The model simulates the dynamics of the interface between the coating and electrolyte. The first version of the model has been implemented in a computational environment, in one and two dimensions, and tested with variable input to detect anomalies in the generated results or convergence issues. In the following steps, the new corrosion experimental results generated by the partners Lurederra, TECNAN and INL will be analyzed and used for the calibration of the model.

Figure 5: Comparison of the interface coating/electrolyte position between the initial time (left) and after 1 year of corrosion (right). The red color represents the anticorrosion layer and the blue color represents the electrolyte. Note that the thickness of the electrolyte layer does not grow with time.

During WP2 different activities have been handle aiming at the fabrication and testing elements individually.

In Task 2.1 and Task 2.2, Lurederra, strongly supported for the coating manufacturer TECNAN, focused on the formulation, application and optimization at lab-scale coating for anticorrosion on metallic materials and antifouling coatings for metallic and plastic materials. In addition, TWI leader of Task 2.3 led the anti-erosion superhydrophobic paints for leading edge protection.

Anticorrosion coatings for metallic elements

The coating would consist in three layers with different chemical composition and therefore different complementary corrosion protections.. The development of the formulations for the different layers shows a very good trend, implying suitable performances for each case, regarding adherence, corrosion resistance, hardness, etc., highlighting the promising results with low temperature matrices, and the process with the self-healing fibers with the main focus on their integration (Figure 1).

Figure 1: Anti-corrosion protection of more than 2000h inside saline mist chamber is shown in several coated samples with the matrix of low curing temperature.

The development of the self-healing nanofibers is also showing promising results according to its specific characterization for its functionality. Moreover, the recent progress for the dispersion of those active fibers is enabling first application tests by spraying, so the multi-layer approach envisaged in the project is getting closer.

Concerning the coating application system, two strategies were mainly designed for this purpose: application via spray gun and application via dip coating. Spraying is the main alternative, since it provides a good surface finish, being applicable for different morphologies and sizes.

Antifouling coatings development, production, application and testing

A fouling-preventing coating for different materials of offshore structures that are submerged are being developed at laboratory scale.

Various highly repellent (hydrophobic and oleophobic) coatings are in development showing also a good adherence and low number of defects. Despite some adjustments are in progress, in a preliminary way, the formulations seem suitable for preventing biofouling formation.

The initial tests to multiple substrates with different chemical nature have been successful. This fact is supported by a considerable number of physicochemical characterizations on different substrates (metal and polymeric). Apart from the experimental work in formulation and characterization, the work related to the collection of reference information has been helpful, highlighting specially the selection of benchmark products from the market.

The application of the anti-fouling coatings is via spray gun (Figure 2), as the most suitable method for this objective, due to its versatility for the different target applications.

Figure 2: Table of spray gun parameters currently defined for the anti-fouling coating system and application test.

Anti-erosion superhydrophobic PU coating for blades: development, production, application and testing

The selection of the wind turbine blade coating matrices were based on the commercially available systems. A survey of the commercial leading edge protection coatings has been carried out and the candidate coating systems were shortlisted. In order to achieve the desired repellence (superhydrophobicity) and erosion resistance, TWI have incorporated functional additives into the selected coating matrices.

The selected additives were based on materials available within the project and which have previously been demonstrated to be platforms for superhydrophobic surfaces. These additives are inorganic metal oxides that are capable of surface functionalization to enable their native hydrophilic surfaces to be transformed into exhibiting hydrophobic behavior. The key additives that are explored are:

  • Stöber derived TWI silica
  • Metal oxides (TECNAN’s silica manufactured using pyrogenic methods and commercially available pyrogenic silica Aerosil 200)

The functionalization of particles – TWI, TECNAN and commercial pyrogenic silica – has demonstrated to significantly change the surface chemistry and thus, uplift the repellence. Also, viscosity versus loading studies (Figure 3 and 4) illustrate the impact of shear rate on viscosity and the difference in behavior between pyrogenic and TWI Stöber silica, suggesting that only TWI silica can be loaded high without a significant change of epoxy or PU physical behavior. The addition, all functionalized silicas added into polysilazane model system improved the repellence characteristics of the whole coating system and thus, it is believed that this will lead to enhanced rain erosion resistance. Besides that, the addition of silica doesn’t affect the coating surface roughness, which means that aerodynamic performance of blades won’t be impacted.

Figure 3: Viscosity of SMS35 HMDZ in butyl acetate as function to shear rate (Image courtesy of TWI Ltd).
Figure 4: Viscosity of HMDZ functionalized silicas evaluated at the constant shear rate (Image courtesy of TWI Ltd).

Synthesis of new concrete materials, testing of increased durability and corrosion resistance

In month 4 within Task 2.4,  ACCIONA along CETMA, INEGI and EDF started developing and testing at laboratory level innovative concrete mixtures with the aim of increasing durability and corrosion resistance. The main effort was focused on the design of:

  • High and ultrahigh concrete material: During this months, the main effort regarding High and Ultrahigh concrete design, were focused on the selection of materials which best fits the offshore application requirements. From the data obtained to date, it could be state that the best materials are a combination of CEM I 52.5 mixed with active additions from waste, a latest generation superplasticizer additive and silica aggregates. This lead to mortars and concretes with higher mechanical properties and workability helping on samples manufacturing process. HPRFRC dosage has been optimized and meets design requirements. It has low potential for cracking according to the ASTM C1581/C1581M Standard. HPFRC optimized dosage has very high resistance against water and chloride penetration (Figure 5).

 
Figure 5: Durability test performed on HPFRC. Left) Penetration of water under pressure equipment. Right) Ring test essay.
  • Alkali Activated concretes that fulfil offshore infrastructure requirements. CETMA, which is responsible for the development of cementless concrete, divided the activity into three main phases:

  1. Binder design (Figure 6)
  2. Mortar design and development
  3. Concrete development and AAM (alkali activated materials) testing

AAM high-density concrete is under development. Although some adjustments are in progress, the binder and mortar formulations have provided good results for the purposes of the project.

Figure 6: Phases of making and testing the binder’s
  • Chlorides ingress characterization for aging concrete in marine environment: EDF is responsible for providing data from ageing concrete samples fabricated directly at the Blyth Wind Farm construction site. 4 months and 1-year aged specimens under permanent immersion have been considered to evaluate the chloride ions ingress. Each specimen of Ф16 cm x10 cm dimensions, is sealed with epoxy resin to allow the penetration of chlorides from a single face, as shown in the figure below. Each sub-specimen has been subjected to the chemical analysis according to the EN14629 standard. Powders corresponding to 10 different depths were manufactured and used to determine the chlorides content. With 9 and 10 tested specimens after respectively 4-months and 1-year of seawater exposure, a comprehensive database of chloride content distribution is available. Some basic processing including the determination of the chloride apparent diffusivity and the prediction of chlorides content evolution over time were performed, in this context. This database will allow the evaluation of new materials (Figure 7).
Figure 7: Chlorides ingress characterization for aged concrete specimens.

Reinforced composites production and testing

In Task 2.5, the following three strategies were planned for new composite laminate production, which involves close collaboration between task leader ÉireComposites (EIRE), TWI and CETMA.

  • Use of nano-SiO2
  • Use of RCF (Recycled Carbon Fibers)
  • Use of /TPR (Thermoplastic Reactive Resin)/Recyclable Epoxy resins

EIRE supplied powder and liquid epoxy resins to TWI and CETMA, for new resin formula and composite reinforcement development. In addition, EIRE defined a preliminary and final material text matrix that will be used to characterize the mechanical and physical properties of the composite laminates produced.

On the other hand, CETMA has defined a preliminary numerical model for the simulation of the resin infusion process, and it has also set up the RCF/Epoxy infusion process with mechanical characterizations in order to adjust the final properties of the new composite formulations.

TWI have characterized and functionalized both, pyrogenic silica and Stöber silica, including wetting behavior and loading effects upon the incorporation to DBEBA epoxy model system. The functionalization has a significant impact on the surface chemistry of those silicas, making them superhydrophobic. Addition of functionalized silicas into DGBE remains a significant challenge, as it raises the viscosity (Figure 8). Nevertheless, this will be mitigated by the development of appropriate silicas incorporation/mixing techniques.

Figure 8: Rheology study of DGEBA resin, 6% SiO2 in DGEBA resin (Image courtesy of TWI Ltd).
 

Preliminary testing of the recycling process and prediction of properties

In Task 2.6 CETMA has carried out rheological and thermal analysis of selected formulations of thermoplastic reactive resins and recyclable thermoset resins. In scale-up activities of the recycling process the most promising recyclable resin and related recycling method will be selected in terms of both initial component performance and industrial effectiveness of the recycling procedure.

Additionally, CETMA also generated a multi-scale numerical model of the recycled material based on RCF. A Representative Volume Elements (RVE) of the recycled material has been generated (Figure 9) and the numerical analyses to calculate the mechanical properties of the composite laminate have been carried out (Figure 10). The good agreement between the numerical and the experimental test results demonstrated the high reliability of the numerical model.

Figure 9: Material properties and microstructure
Figure 10: Numerical model and results

During the first four months of the project, exhaustive search, analysis and compilation of relevant information has been performed in order to define key aspects. Concretely, the technical requirements of the new materials to be developed, the requirements related to monitoring and modelling, a mapping of relevant standards, the specifications of the demo sites and the plan for technology risk mitigation.


Definition of requirements for new materials

In task 1.1., TECNAN along with other partners specialized in anticorrosion and antifouling coatings as well as in coatings and composites for the blades, completed the very first part of the work. The aim was to provide an overview of the characteristics of new materials and monitoring procedures.

In the very first phase of WP1, exhaustive researches were carried out to provide guidelines and the technical requirements of the new materials to be developed. This first step will ensure that the project technologies can be implemented successfully. As relevant information compiled for each technology, the main technical challenges of the project where highlighted:

  • Anticorrosion coatings
  • Antifouling coatings
  • Coatings for the blades
  • Composite for the blades
  • Concrete enhancements

Definition of requirements related with monitoring and predictive

From M1 to M4, Task 1.2 focused on the definition of the requirements for the Structural Health Monitoring systems and the modelling activities to be developed within WP3. The results of the task resulted in a summary of the identified requirements. The MAREWIND project will develop two types of monitoring system:

  • Full-filed non-destructive testing (NDT), such as infrared thermography and 3D digital image correlation (DIC), supported by unmanned aerial vehicles (UAVs). INEGI started the definition of requirement of the NDT system by reviewing those standards related to NDT procedures and thermography methodology. They also reviewed the European and local regulations and requirements for the operation of unmanned aircraft at the demonstration sites.

   
  • Remote optical sensors, such as fibre Bragg grating (FBG) and distributed fibre optic (DFO) sensors, integrated into blades and concreted-based structural components to provide real-time feedback on deformation and structural integrity state of components. The monitoring system based on remote optical sensors will be developed by CETMA and INEGI, with CETMA focusing on sensorization of concrete-based structural components and INEGI focusing on blade representative components.

   

Standards mapping

In Task 1.3 all the partners compiled the relevant standards and regulations related to the project developments. The early identification of standards will also allow a future identification of possible standardization gaps. Relevant partners from the project contributed to the review, checking the standards already implemented their entities, and also the new potential ones that could be of interest in relation to the technologies of the project.

Two main compilations were made:

  • DNV guidelines compliance, crucial to ensure posterior market implementation and the standards map.
 
  • Innovation technologies where no standards and regulations could be found were identified.
 

Specifications for demonstrations sites

In the next phase in Task 1.4, after some discussions, a final overview of the potential demonstration sites – onshore and offshore – was given. For the offshore testing locations, various potential places are contemplated including the north of Portugal, the north of Spain and Canary Islands. The onshore wind farms are the second group of locations, a pre‐selection of onshore locations related to the real condition tests of the project was presented. These locations are divided in two groups the North of Spain wind farms and the South of Spain wind farms. The early contemplations are based on the climate of these areas since it could be very valuable for real environment tests.

W2Power floating wind platforms: example of the offshore structures pre-selected by project partners for the validation of the developments.
   

As of April 2021, the MAREWIND consortium has started working on WP3 predictive modelling for preventive maintenance of wind energy. This part of the work plan focuses on the development of technologies for monitoring the structural health status of wind offshore facilities. It also develops mathematical models aimed to representing different key aspects related to the durability and maintenance of offshore structures and materials. During the first months, the involved partners led by IDENER have set the bases for the future work.


Monitoring technologies

INEGI will develop a blade monitoring technology that uses cameras mounted onto drones to acquire images (visible and infrared) of the rotating blades. The images will be then digitally analysed for the detection of sub-surface voids, delamination and displacements. INEGI has already designed a lab-scale setup and selected equipment to be used. It also features cameras, synchronization controllers, drone and a representative rotating blade. INEGI will use this lab setup during the upcoming months to test and analyse different configurations of the cameras. That also includes “floating” cameras that will simulate the operation of a camera mounted in a drone.

MAREWIND consortium will be also developing monitoring technologies based on fibre optic sensors. The sensors will be embedded into representative concrete and blade components to build a remote real-time sensing system, able to early detect diseases or damages.

Firstly, CETMA will focus on the installation of sensors into concrete-based components, while INEGI will focus on blade composite elements. CETMA already started the preliminary design of the sensor system, paying special attention to the characteristics and size of the prototypes that will be sensorized in the project.

Likewise, INEGI started the design of the sensor system by defining the sensor placement and equipment for each parameter of assessment. During the following months, CETMA and INEGI will perform the first lab-scale trials of the designed systems.


Water simulations around gravity-based structures

Furthermore, INEGI has started working on the simulations of the water column around the gravity-based structure (GBS) by using computational fluid dynamics. The simulations involved numerical modelling of the flow at the bottom of the sea influenced by waves and currents.

The modelling procedure for such a complex and vast fluid domain was divided in two parts to reduce considerably the computational cost of a complete Computational fluid dynamics 3D model with complex geometries.

  1. The first model was developed in 2D. The main goal was to obtain velocity profiles each time step that captured the effects of surface waves at the bottom of the domain. The effects of currents would be considered directly in the second part of the model.
  2. The 2D model would produce velocity profiles in each time step for the 15-sea state and 3 depths in a total of 15 representative cases. They could be applied to an inlet boundary condition of a 3D model that would include the GBS. This approach reduced the computational cost as the 3D domain could have a limited dimension and could be considered totally submerged, without the need for the high-demanding VOF (Volume of Fluid) multiphase model. In the Figure 1 it is shown the 3D in its final configurations with the main boundary conditions.
Figure 1. Domain and boundary conditions for the second part of the model.

The experts obtained results from the hydrodynamics analysis that was performed using CFD. The collected outputs were pressure maps for each selected case in the transient form. In order to illustrate the results, a static pressure contour for sea state 50 m of depth and current of 1 m/s is displayed is displayed in Figure 2.

Figure 2. Example of results of the computational fluid dynamics model.

Structural Analyses on Composite Blades

RINA will develop a finite element computational model of the reinforced fibre composite developed in the MAREWIND project. The overall model will interconnect three successive sub-models at different scales of the composite and will allow the simulation of the mechanical behaviour of the composite blades.

In the first step of the task, RINA has started the setup of a mathematical model. The model should be of a suitable representative volume element (RVE) of an elementary composite specimen, considering the constituent materials (matrix and fibres) and their combination (Figure 3).

Figure 3. Selection of matrix and fibre materials of the representative volume element

In the upcoming months, RINA will implement this numerical model with the project data. Thus,  allowing the calculation of the properties of an equivalent homogeneous material using the known properties of its base materials.


Modelling of corrosion in atmosphere-exposed metallic structures

During the first months, IDENER started the construction of a corrosion mathematical model by defining a first simple scenario with a single anticorrosion coating layer (sacrificial layer). The approach selected for the model will focus on the description of the dynamics of the interface between the coating and electrolyte, which will be under the effects of corrosion. Once the computational implementation of this first approximation is finished, the complexity of the model will be gradually increased by including the other layers of the anticorrosion protection, such as the self-healing layer.